Researchers at the University of Illinois at Urbana-Champaign have developed a powerful new platform of polyureas that enable systems that are hydrolyzable, self-healing,...
Researchers at the University of Illinois at Urbana-Champaign have developed a powerful new platform of polyureas that enable systems that are hydrolyzable, self-healing, and malleable, opening exciting applications in the packaging, coating, and adhesives industries. In this new class of polyureas, a bulky substituent is attached to one of the nitrogen atoms of the urea bond and destabilizes the typically stable linkage leading to dynamic dissociation. The polymers can be built from the vast library of isocyanate monomers already developed for the polyurea and polyurethane industries, yielding a wide range of materials with varying, engineered characteristics.
Hydrolyzable Polyureas (TF14085)
Hydrolyzable polymers are currently used in the agriculture and food industries as environmentally friendly plastics and packaging materials and in the biomedical field as drug delivery systems, surgical sutures, and scaffolds for tissue engineering. However, most hydrolyzable polymers, based on polyester materials or materials containing anhydride, acetal, ketal, or imine linkages, are synthesized via condensation or ring-opening polymerizations, often requiring high temperature conditions and catalysts and resulting in by-products. In contrast, because polyureas are made via a simple and clean chemistry without catalysts or by-products, hydrolyzable polyureas offer users the ability to tune polymer systems to specific applications without involving complex chemistries.
In this platform of polyureas, the destabilization introduced by the bulky substituent on the nitrogen of the urea bond leads to dynamic dissociation to the corresponding amines and isocyanates, with the isocyanates further undergoing irreversible hydrolysis in aqueous solution and complete degradation of the polyurea.
Incorporating the appropriate bulky substituents into polyureas enables polymers that can undergo autonomous, catalyst-free repair at room/low temperatures without the use of microcapsule healing agents, special precursors or customized laboratory/environmental conditions. Commercially available materials are used to produce self-healing polymers with capabilities to re-heal multiple times.
Here the bulky substituents are chosen so that (i) the dissociation and reverse (polymer-forming) reactions are rapid and (ii) the polymer-forming reaction is highly favored, thereby insuring optimum bulk mechanical properties of the polymer. Conventional polyureas and poly(urethane-urea)s can thus readily be made dynamic and self-healing while maintaining their stability by replacing regular amines with amines containing bulky substituents. By tuning the substituent, the dynamic properties of the polymer and its mechanical properties can be controlled.
Dynamic Urea Bond for the Design of Reversible and Self-Healing Polymers Hanze Ying, Yanfeng Zhang, and Jianjun Cheng Nature Communications 2014 5:3218 doi: 10.1038/ncomms4218
The polyurea systems can also be made malleable and recyclable by exploiting the reversible nature of the urea bond with the bulky subsituent. The cross-linked systems bearing the bulky substituents can be ground into powders and pressed/molded as shown below.
Dr. Suslick has developed a method to form polymer microcolumns for portable and disposable gas chromatography. Using sacrificial materials as a template, 2D and 3D...
Dr. Suslick has developed a method to form polymer microcolumns for portable and disposable gas chromatography. Using sacrificial materials as a template, 2D and 3D microcolumns are formed to separate volatile chemicals.
This method is cost effective and easy to implement.
Dr. Braun has developed a material that can polymerize and de-polymerize using two distinct triggers. By building on reversible Spyropyan chemistry, Dr. Braun has made...
Dr. Braun has developed a material that can polymerize and de-polymerize using two distinct triggers. By building on reversible Spyropyan chemistry, Dr. Braun has made polymers that can be multiplied reversibly.
This invention can be applied to reversible adhesives, self-toughening or self-strengthening materials, and more.
Dr. Moore from the University of Illinois at Urbana-Champaign has developed a method for enhancing the thermal stability of cyclic poly(phthalaldehyde) (“cPPA”). cPPA is a...
Dr. Moore from the University of Illinois at Urbana-Champaign has developed a method for enhancing the thermal stability of cyclic poly(phthalaldehyde) (“cPPA”). cPPA is a transient material which is capable of depolymerizing in response to a stimulus (e.g., acid, heat). Until now, the low degradation temperature of cPPA has precluded thermal processing of the material. Additionally, cPPA’s unpredictable stability and thermal degradation behavior prevented standardization. The inventors identified a method for stabilizing cPPA to enable thermal processing of the material. Thermal processing allows more complex architectures to be fabricated from cPPA, these architectures can then undergo triggered depolymerization to break down the material. Potential applications for this material include disappearing drones and lithography.
Dr. Zimmerman from the University of Illinois has developed a new class of compounds for the fabrication of repurposable polyurethane materials. The polyurethanes made...
Dr. Zimmerman from the University of Illinois has developed a new class of compounds for the fabrication of repurposable polyurethane materials. The polyurethanes made from these compounds can be decomposed, under mild conditions, to useful alternative compounds and reused as adhesives with superior strength. Additionally, the polyurethanes made from these compounds exhibit nearly identical properties to those currently used in industry and are vitrimers that can self-heal.
Benefit
This invention minimizes the waste associated with the production and use of polyurethanes.
Application
Primary use is fabrication of polyurethane elastomers and foams for a variety of industrially relevant applications.
These relevant applications include manufacture of high-resilience foam seating, rigid foam insulation panels, microcellular foam seals and gaskets, durable elastomeric wheels and tires, automotive suspension bushings, electrical potting compounds, high-performance adhesives, surface coatings and surface sealants, synthetic fibers, carpet underlay, hard-plastic parts, condoms, and hoses.
Researchers from the University of Illinois have developed a new technique for fabricating elastomeric materials, namely 1,4-polybutadiene and co-polymers of 1,4-...
Researchers from the University of Illinois have developed a new technique for fabricating elastomeric materials, namely 1,4-polybutadiene and co-polymers of 1,4-polybutadiene. The technique employs frontal ring-opening metathesis polymerization allowing for a rapid and energy efficient means of producing these materials. The materials produced by this technique may be used to fabricate a variety of products including tires, tubes, belts, gaskets, etc. This technology also allows for the rapid fabrication of elastomeric materials with shape memory properties.
Dr. Damien Guironnet from the University of Illinois has developed a chemical recycling method for upcycling propylene and isobutene solid wastes. This technique may be...
Dr. Damien Guironnet from the University of Illinois has developed a chemical recycling method for upcycling propylene and isobutene solid wastes. This technique may be used to produce higher value feedstock materials (e.g., propylene and isobutene) from polyethylene and polypropylene with high selectivity. This process achieves high yield, in comparison with other chemical recycling techniques, through a combination of reactor design, catalyst selection, and process optimization.
